Reading the current system audio volume
MPMusicPlayerController *iPod = [MPMusicPlayerController iPodMusicPlayer];
float volumeLevel = iPod.volume;
NSLog(@"Volume: %f", volumeLevel);
You need to import the MediaPlayer framework and use:
#import <MediaPlayer/MediaPlayer.h>
Other resources
http://stackoverflow.com/questions/7255006/get-system-volume-ios